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On what Grounds can you appeal?

This is not a precise science but the best guide is contained within Section 25 of the Matrimonial Causes Act 1973. The judge needed to take into account each of those factors eg the age and health, the financial needs, earning capacity etc. One is looking for an error in law such as a procedural issue or some miscalculation. But remember, it is also possible to apply to have an Order set aside if the other party has materially misled the Court (as can often happen!)